Rubbed polyimide surface studied by sum-frequency vibrational spectroscopy

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초록

Surface-specific sum-frequency vibrational spectroscopy was used to study the structure of a rubbed polyimide surface. The spectra showed that the polymer backbones were well aligned by rubbing along the rubbing direction, and the imide cores were inclined toward the surface plane with a broad distribution. Quantitative analysis yields an approximate orientational distribution function for the aligned imide cores and the backbones.

키워드

LIQUID-CRYSTAL ALIGNMENTMOLECULAR-ORIENTATIONPRETILT ANGLEFILMSLAYERCONFORMATIONREFLECTIONMONOLAYER
제목
Rubbed polyimide surface studied by sum-frequency vibrational spectroscopy
저자
Kim, DOh-e, MShen, YR
DOI
10.1021/ma0100908
발행일
2001-12-18
유형
Article
저널명
Macromolecules
34
26
페이지
9125 ~ 9129