The preparation of stable aziridinium ions and their ring-openings

  • Kim, Yongeun
  • Ha, Hyun-Joon
  • Yun, Sae Young
  • Lee, Won Koo
Citations

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초록

The reaction of enantiomerically, pure 2-substituted 1-phenylethyl-aziridine with methyl trifluoromethanesulfonate generated a stable methylaziridinium ion, which was reacted with various external nucleophiles, including nitrile, to yield synthetically valuable and optically. pure acyclic amine derivatives in a completely regio- and stereoselective manner.

키워드

EFFICIENT SYNTHESISSTEREOSELECTIVE-SYNTHESISCHIRAL AZIRIDINES2-ACYLAZIRIDINES
제목
The preparation of stable aziridinium ions and their ring-openings
저자
Kim, YongeunHa, Hyun-JoonYun, Sae YoungLee, Won Koo
DOI
10.1039/b809124b
발행일
2008
유형
Article
저널명
Chemical Communications
36
페이지
4363 ~ 4365