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Aziridines as Versatile C(sp<SUP>3</SUP> ) Precursors in Transition-Metal-Catalyzed Cross-Coupling Strategies
- Kim, Eunbi;
- Baik, Eunji;
- Shin, Jihye;
- Hwang, Junha;
- Dongbang, Sun
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1초록
Aziridines, which serve as valuable scaffolds in numerous pharmaceuticals and bioactive molecules, have emerged as highly efficient C(sp(3)) precursors in the realm of organic chemistry. Particularly, employing aziridines as versatile electrophiles in transition-metal-catalyzed cross-coupling has enabled precise control over the regiochemistry in the formation of new C(sp(3))-C, -Si, and -B bonds. This review explores recent innovative aziridine cross-coupling approaches using Ni or Pd catalysis, highlighting initial findings of new mechanistic approaches and delineating distinct catalytic pathways.
키워드
aziridines; cross-coupling; transition-metal catalysis; cross-electrophile coupling; metallaphotoredox reactions; amines; N-SULFONYLAZIRIDINES; VINYL AZIRIDINES; 2-ARYLAZIRIDINES; FUNCTIONALIZATION; AMINO; REGIOSELECTIVITY; PHENETHYLAMINES; GENERATION; ALKYLATION; REACTIVITY
- 제목
- Aziridines as Versatile C(sp<SUP>3</SUP> ) Precursors in Transition-Metal-Catalyzed Cross-Coupling Strategies
- 저자
- Kim, Eunbi; Baik, Eunji; Shin, Jihye; Hwang, Junha; Dongbang, Sun
- 발행일
- 2025-03-18
- 유형
- Review
- 저널명
- Synthesis
- 권
- 57
- 호
- 06
- 페이지
- 1081 ~ 1101