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One-pot solvent-free reductive amination with a solid ammonium carbamate salt from CO2 and amine
- Kang, Philjun;
- Lee, Kyu Myung;
- Lee, Won Koo;
- Lee, Kyu Hyung;
- Lee, Byeongno;
- 외 2명
Citations
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9초록
Many amines are liquid and their handling is inconvenient compared with the corresponding solids. We transformed a liquid (S)-(-)-1-phenylethylamine 1 to the corresponding neutral solid form 2 by reacting with carbon dioxide. We performed reductive amination of 2 with various aldehydes 3 under solvent-free conditions to provide secondary amines 5 in high yields.
키워드
CARBON-DIOXIDE; PALLADIUM; ALDEHYDES; ESTER; HYDROGENATION; KETONES; ACID; DERIVATIVES; HYDRAZINE; CHLORIDE
- 제목
- One-pot solvent-free reductive amination with a solid ammonium carbamate salt from CO2 and amine
- 저자
- Kang, Philjun; Lee, Kyu Myung; Lee, Won Koo; Lee, Kyu Hyung; Lee, Byeongno; Cho, Jaeheung; Hur, Nam Hwi
- 발행일
- 2014
- 유형
- Article
- 저널명
- RSC Advances
- 권
- 4
- 호
- 86
- 페이지
- 46203 ~ 46207