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A novel synthesis of 5-functionalized oxazolidin-2-ones from enantiomerically pure 2-substituted N-[(R)-(+)-α-methylbenzyl]aziridines
- Sim, TB;
- Kang, SH;
- Lee, KS;
- Lee, WK;
- Yun, H;
- 외 2명
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90초록
5-Funtionalized enantiomerically pure oxazolidin-2-ones were prepared in one pot from commercially available chiral aziridines bearing an electron-withdrawing group at C-2 with retention of the configuration in high yields by regioselective aziridine ring-opening followed by intramolecular cyclization.
키워드
XYLOSE DERIVED OXAZOLIDIN-2-ONES; CHIRAL AUXILIARIES; EFFICIENT SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC-SYNTHESIS; DERIVATIVES; 3-ARYL-2-OXOOXAZOLIDINES; ANTIBACTERIALS; AZIRIDINES; INHIBITOR
- 제목
- A novel synthesis of 5-functionalized oxazolidin-2-ones from enantiomerically pure 2-substituted N-[(R)-(+)-α-methylbenzyl]aziridines
- 저자
- Sim, TB; Kang, SH; Lee, KS; Lee, WK; Yun, H; Dong, YK; Ha, HJ
- 발행일
- 2003-01-10
- 유형
- Article
- 권
- 68
- 호
- 1
- 페이지
- 104 ~ 108