A Polar and Chiral Indium Telluride Featuring Supertetrahedral T2 Clusters and Nonlinear Optical Second Harmonic Generation

Zhang, Qichun; Chung, In; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G.

doi:10.1021/cm8027516

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A Polar and Chiral Indium Telluride Featuring Supertetrahedral T2 Clusters and Nonlinear Optical Second Harmonic Generation

Zhang, Qichun;
Chung, In;
Jang, Joon I.;
Ketterson, John B.;
Kanatzidis, Mercouri G.

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WEB OF SCIENCE

96

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SCOPUS

102

초록

The "KIn2" Zintl phase activates tellurium under solvothermal conditions and yields the compound {[In(en)(3)][In5Te9(en)(2)] center dot 0.5en}(n) (en = ethylenediamine). The material has both a polar and chiral layered framework and exhibits type 1 phase-matchable strong second harmonic generation (SHG) response.

키워드

CRYSTAL-STRUCTURE; ELECTROCHEMICAL SYNTHESIS; METAL POLYCHALCOGENIDES; COORDINATION CHEMISTRY; CHALCOGENIDE CLUSTERS; SOLID-STATE; SULFIDE; RB; REACTIVITY; ANIONS

제목: A Polar and Chiral Indium Telluride Featuring Supertetrahedral T2 Clusters and Nonlinear Optical Second Harmonic Generation

저자: Zhang, Qichun; Chung, In; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G.

DOI: 10.1021/cm8027516

발행일: 2009-01-13

유형: Article

저널명: Chemistry of Materials

권: 21

호: 1

페이지: 12 ~ 14