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A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster:: [MV][{Mn(CH3OH)2}{Re6Se8(CN) 6}]
- Kim, Sehye;
- Kim, Youngmee;
- Lee, Junghyun;
- Shin, Woonsup;
- Lee, Minyung;
- 외 1명
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21초록
A new layered compound, [MV][{Mn(CH3OH)(2)} {Re6Se8(CN)(6)}] (1) consists of a layer alternately knitted by hexarhenium cluster and Mn complex, and MV2+ cations (methyl viologen dication = 1,1'-dimethyl-4,4'-bipyridilium dication) reside between the layers. The title compound I is the first layered framework containing cyano-hexarhenium clusters with photoactive guest molecules, MV2+. The MV2+ can be partly exchanged by H2TMB2+ (N,N,N',N'-tetramethylbenzidine dication) to form a compound [H2TMB2+](x)[MV2+](1-x) [{Mn(CH3OH)(2)} {Re6Se8(CN)(6)}] (2) showing an electronic interaction between the layered framework and [H2TMB](2+) cation. (C) 2006 Elsevier B.V. All rights reserved.
키워드
ELECTRON-TRANSFER REACTIONS; LIVED ION-PAIRS; CRYSTAL-STRUCTURE; RHENIUM CLUSTER; ARTIFICIAL PHOTOSYNTHESIS; MONOPHOTONIC IONIZATION; METHYL-VIOLOGEN; POLAR-SOLVENTS; RADICAL-CATION; FRAMEWORK
- 제목
- A new self-assembled inorganic-organic hybrid layered compound containing hexarhenium cluster:: [MV][{Mn(CH3OH)2}{Re6Se8(CN) 6}]
- 저자
- Kim, Sehye; Kim, Youngmee; Lee, Junghyun; Shin, Woonsup; Lee, Minyung; Kim, Sung-Jin
- 발행일
- 2007-04-20
- 유형
- Article
- 권
- 360
- 호
- 6
- 페이지
- 1890 ~ 1894