KF•B(OH)3: a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency

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초록

A designed material with large birefringence and remarkable deep-ultraviolet transparency, KF center dot B(OH)(3), has been discovered. The well-aligned [F center dot B(OH)(3)](-) layers endow a very large bandgap (7.63 eV), comparably large birefringence (0.114 @1064 nm), and the reinforced interlayer bonding of ca. 2.16 x KBe2BO3F2.

키워드

NONLINEAR-OPTICAL MATERIALDENSITY-FUNCTIONAL THEORY2ND-HARMONIC GENERATIONNONCENTROSYMMETRIC MATERIALSGROWTHDESIGNMEMBER
제목
KF•B(OH)3: a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency
저자
Li, YangChen, XinglongOk, Kang Min
DOI
10.1039/d2cc03495f
발행일
2022-08-04
유형
Article
저널명
Chemical Communications
58
63
페이지
8770 ~ 8773