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Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3
- Zhang, Qichun;
- Chung, In;
- Jang, Joon I.;
- Ketterson, John B.;
- Kanatzidis, Mercouri G.
Citations
WEB OF SCIENCE
228Citations
SCOPUS
234초록
The new cation [Sb7S8Br2](3+) has a double-cubane structure and forms as the [AlCl4](-) salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 degrees C. The compound is noncentrosymmetric with space group P2(1)2(1)2(1) and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.
키워드
GENERATION; CS; NANORODS; FIGURE; LAYERS; LIGHT
- 제목
- Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3
- 저자
- Zhang, Qichun; Chung, In; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G.
- 발행일
- 2009-07-29
- 유형
- Article
- 권
- 131
- 호
- 29
- 페이지
- 9896 ~ +