Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

Zhang, Qichun; Chung, In; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G.

doi:10.1021/ja903881m

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Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

Zhang, Qichun;
Chung, In;
Jang, Joon I.;
Ketterson, John B.;
Kanatzidis, Mercouri G.

Citations

WEB OF SCIENCE

229

Citations

SCOPUS

235

초록

The new cation [Sb7S8Br2](3+) has a double-cubane structure and forms as the [AlCl4](-) salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 degrees C. The compound is noncentrosymmetric with space group P2(1)2(1)2(1) and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.

키워드

GENERATION; CS; NANORODS; FIGURE; LAYERS; LIGHT

제목: Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)3

저자: Zhang, Qichun; Chung, In; Jang, Joon I.; Ketterson, John B.; Kanatzidis, Mercouri G.

DOI: 10.1021/ja903881m

발행일: 2009-07-29

유형: Article

저널명: Journal of the American Chemical Society

권: 131

호: 29

페이지: 9896 ~ +

언어: ENG

출판사: American Chemical Society

발행국가: 미국

ISSN: E 1520-5126
P 0002-7863