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Alkyl-chain dividing layer at an alcohol/ionic liquid buried interface studied by sum-frequency generation vibrational spectroscopy
- Iwahashi, Takashi;
- Sakai, Yasunari;
- Kanai, Kaname;
- Kim, Doseok;
- Ouchi, Yukio
Citations
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20Citations
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23초록
We demonstrate for the first time the formation of a non-polar alkyl-chain dividing layer between a room-temperature ionic liquid (RTIL) and an n-alcohol. This newly described non-polar interfacial layer, which should be more hydrophobic than both RTIL and alcohol phases, might find applications in liquid/liquid reaction systems, or serve as a soft nano-functional space.
키워드
IONIC LIQUIDS; AIR/LIQUID INTERFACE; STRETCHING MODES; WATER-INTERFACE; LOCAL-STRUCTURE; SIMULATIONS; ADSORPTION; CRYSTALS; SURFACES; SI(100)
- 제목
- Alkyl-chain dividing layer at an alcohol/ionic liquid buried interface studied by sum-frequency generation vibrational spectroscopy
- 저자
- Iwahashi, Takashi; Sakai, Yasunari; Kanai, Kaname; Kim, Doseok; Ouchi, Yukio
- 발행일
- 2010
- 유형
- Article
- 권
- 12
- 호
- 40
- 페이지
- 12943 ~ 12946
- 언어
- ENG
- 출판사
- Royal Society of Chemistry
- 발행국가
- 영국
- 분량
- 4 페이지
- ISSN
- E 1463-9084
P 1463-9076