Alkyl-chain dividing layer at an alcohol/ionic liquid buried interface studied by sum-frequency generation vibrational spectroscopy

  • Iwahashi, Takashi
  • Sakai, Yasunari
  • Kanai, Kaname
  • Kim, Doseok
  • Ouchi, Yukio
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22

초록

We demonstrate for the first time the formation of a non-polar alkyl-chain dividing layer between a room-temperature ionic liquid (RTIL) and an n-alcohol. This newly described non-polar interfacial layer, which should be more hydrophobic than both RTIL and alcohol phases, might find applications in liquid/liquid reaction systems, or serve as a soft nano-functional space.

키워드

IONIC LIQUIDSAIR/LIQUID INTERFACESTRETCHING MODESWATER-INTERFACELOCAL-STRUCTURESIMULATIONSADSORPTIONCRYSTALSSURFACESSI(100)
제목
Alkyl-chain dividing layer at an alcohol/ionic liquid buried interface studied by sum-frequency generation vibrational spectroscopy
저자
Iwahashi, TakashiSakai, YasunariKanai, KanameKim, DoseokOuchi, Yukio
DOI
10.1039/c0cp00520g
발행일
2010
유형
Article
저널명
Physical Chemistry Chemical Physics
12
40
페이지
12943 ~ 12946