Experimental and Theoretical Investigations for the Quaternary Mixed-Cation Zintl Phase Ca1.82(1)Eu0.18CdSb2

Kim, Kiwon; Jo, Hongil; Ok, Kang Min; You, Tae-Soo

doi:10.1002/bkcs.11970

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Experimental and Theoretical Investigations for the Quaternary Mixed-Cation Zintl Phase Ca1.82(1)Eu0.18CdSb2

Kim, Kiwon;
Jo, Hongil;
Ok, Kang Min;
You, Tae-Soo

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WEB OF SCIENCE

8

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8

초록

A quaternary Zintl phase Ca1.82(1)Eu0.18CdSb2 with the Ca2+/Eu2+ mixed-cations was successfully synthesized by the Pb metal-flux method and characterized by PXRD and SXRD analyses. The particular site-preference of Ca and Eu was nicely elucidated by both of the size-factor and the electronic-factor criteria.

키워드

Zintl phase; Thermoelectric material; Single-crystal; Site-preference; Electronic structure; THERMOELECTRIC PROPERTIES; ELECTRONIC-STRUCTURES; EFFICIENCY; CRYSTAL

제목: Experimental and Theoretical Investigations for the Quaternary Mixed-Cation Zintl Phase Ca1.82(1)Eu0.18CdSb2

저자: Kim, Kiwon; Jo, Hongil; Ok, Kang Min; You, Tae-Soo

DOI: 10.1002/bkcs.11970

발행일: 2020-02

유형: Article

저널명: Bulletin of the Korean Chemical Society

권: 41

호: 2

페이지: 245 ~ 247