Observation of photoluminescence in polypyrrole micelles

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35

초록

Photoluminescence (PL) was observed from micelles of polypyrrole without substituent groups. CHCI3 and CCI4 as well as 2,2,6,6-tetramethyl-1-piperidinyloxy (TEMPO) showed a typical fluorescence quenching behavior that can be observed when quencher molecules are added to a micellar solution of fluorescent material. At higher concentrations, the PL intensity decreased due to quenching in the aggregate phase and self-absorption. The PL intensity,varied depending upon the solvent in the order of dimethyl sulfoxide (DMSO) > N,N-dimethylformamide (DMF) > N-methyl-2-pyrrolidinone (NMP) > ethanol > toluene > tetrahydrofuran (THF). (c) 2005 Elsevier B.V. All rights reserved.

키워드

polypyrrole micellesphotoluminescence of polypyrrolephotoluminescence quenching in micelleshighly soluble polypyrroleanionic surfactant-doped polypyrroleSOLUBLE POLYPYRROLEELECTROCHEMICAL POLYMERIZATIONAROMATIC-HYDROCARBONSCHARGE-TRANSPORTFLUORESCENCESOLVENTCHLOROFORMAMINESPOLYMERSBEHAVIOR
제목
Observation of photoluminescence in polypyrrole micelles
저자
Jang, KSKo, HCMoon, BLee, H
DOI
10.1016/j.synthmet.2005.01.013
발행일
2005-04-30
유형
Article
저널명
Synthetic Metals
150
2
페이지
127 ~ 131