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Stereoselective Pd-catalyzed etherification and asymmetric synthesis of furanomycin and its analogues from a chiral aziridine
- Jung, Jae-Hoon;
- Yoon, Doo-Ha;
- Lee, Kyuwoong;
- Shin, Hyeonah;
- Lee, Won Koo;
- 외 2명
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12초록
A chiral aziridine was utilized for the synthesis of the anti-bacterial natural amino acid L-(+)-furanomycin, and its analogues including 5'-epi-furanomycin and norfuranomycin. Key steps of this synthesis are the stereoselective Pd-catalyzed etherification for diallyl ethers and ring closing metathesis.
키워드
TRANSFER-RNA SYNTHETASE; AMINO-ACID-ANALOGS; ALLYLIC ETHERIFICATION; EFFICIENT SYNTHESIS; (+)-FURANOMYCIN; DERIVATIVES; ISOLEUCINE; CHEMISTRY; ALCOHOLS; ZINC
- 제목
- Stereoselective Pd-catalyzed etherification and asymmetric synthesis of furanomycin and its analogues from a chiral aziridine
- 저자
- Jung, Jae-Hoon; Yoon, Doo-Ha; Lee, Kyuwoong; Shin, Hyeonah; Lee, Won Koo; Yook, Cheol-Min; Ha, Hyun-Joon
- 발행일
- 2015-08-14
- 유형
- Article
- 권
- 13
- 호
- 30
- 페이지
- 8187 ~ 8195