Gold/Copper Dual-Catalyzed Annulation of Arynes with Phosphites: A Synthetic Strategy for Dibenzophospholes

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초록

A synthetic approach to dibenzophospholes was developed via the gold- and copper-catalyzed annulation reactions of arynes and phosphites. The reaction conditions demonstrated a broad functional group tolerance, enabling the synthesis of a diverse range of dibenzophosphole 5-oxides. This method is useful for preparing dibenzophospholes with unique optical and electronic properties.

키워드

P-ARYLATIONALKYNE
제목
Gold/Copper Dual-Catalyzed Annulation of Arynes with Phosphites: A Synthetic Strategy for Dibenzophospholes
저자
Shin, DonghwaHan, Seo-Jung
DOI
10.1021/acs.orglett.5c01178
발행일
2025-04
유형
Article
저널명
Organic Letters
27
18
페이지
4767 ~ 4771