Composition variations in Cu2ZnSnSe4 thin films analyzed by X-ray diffraction, energy dispersive X-ray spectroscopy, particle induced X-ray emission, photoluminescence, and Raman spectroscopy

  • Nam, Dahyun
  • Opanasyuk, A. S.
  • Koval, P. V.
  • Ponomarev, A. G.
  • Jeong, Ah Reum
  • ... Cheong, Hyeonsik
  • 외 2명
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초록

Compositional and structural studies of Cu2ZnSnSe4 (CZTSe) thin films were carried out by X-ray diffraction, energy dispersive X-ray spectroscopy (EDS), particle induced X-ray emission (PIXE), photoluminescence, and Raman spectroscopy. CZTSe thin films with different compositions were deposited on sodalime glass by co-evaporation. The composition of the films measured by two different methods, EDS and PIXE, showed significant differences. Generally, the Zn/Sn ratio measured by EDS is larger than that measured by PIXE. Both the micro-PIXE and the micro-Raman imaging results indicated the compositional and structural inhomogeneity of the sample. (C) 2014 Elsevier B.V. All rights reserved.

키워드

Copper-zinc-tin selenideThin filmsX-ray diffractionEnergy dispersive X-ray spectroscopyRaman spectroscopyConfocal microscopyParticle induced X-ray emissionPhotoluminescenceSOLAR-CELLGROWTH
제목
Composition variations in Cu2ZnSnSe4 thin films analyzed by X-ray diffraction, energy dispersive X-ray spectroscopy, particle induced X-ray emission, photoluminescence, and Raman spectroscopy
저자
Nam, DahyunOpanasyuk, A. S.Koval, P. V.Ponomarev, A. G.Jeong, Ah ReumKim, Gee YeongJo, WilliamCheong, Hyeonsik
DOI
10.1016/j.tsf.2014.03.079
발행일
2014-07-01
유형
Article
저널명
Thin Solid Films
562
페이지
109 ~ 113