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Low valent phosphorus in the molecular anions [P5Se12]<SUP>5-</SUP> and β-[P6Se12]<SUP>4-</SUP>:: phase change behavior and near infrared second harmonic generation
- Chung, In;
- Jang, Joon I.;
- Gave, Matthew A.;
- Weliky, David P.;
- Kanatzidis, Mercouri G.
Citations
WEB OF SCIENCE
42Citations
SCOPUS
43초록
The caesium salts of the novel molecular anions [P5Se12](5-) and [P6Se12](4-) are phase change materials and exhibit near infrared, non-linear optical second harmonic generation; [P5Se12](5-) is a coordination complex with an octahedral P3+ center chelated by two [P2Se6](4-) ligands whereas [P6Se12](4-) features a [P-2](4+) dimer chelated by two [P2Se6](4-) ligands.
키워드
CRYSTAL-STRUCTURE; RB; SELENOPHOSPHATES; FRAGMENTS; SN2P2S6; CENTERS; STORAGE; CS
- 제목
- Low valent phosphorus in the molecular anions [P5Se12]<SUP>5-</SUP> and β-[P6Se12]<SUP>4-</SUP>:: phase change behavior and near infrared second harmonic generation
- 저자
- Chung, In; Jang, Joon I.; Gave, Matthew A.; Weliky, David P.; Kanatzidis, Mercouri G.
- DOI
- 10.1039/b714301j
- 발행일
- 2007
- 유형
- Article
- 호
- 47
- 페이지
- 4998 ~ 5000