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Asymmetric synthesis of 1-deoxyazasugars from chiral aziridines
- Singh, Alok;
- Kim, Bongchan;
- Lee, Won Koo;
- Ha, Hyun-Joon
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39초록
A general and facile synthesis of enantiopure 1-deoxyazasugars was achieved from stereoselective dihydroxylation of a common synthetic intermediate, piperidine ring fused oxazolidin-2-one, originating from a commercially available starting substrate, chiral aziridine-2-carboxylate, in high yields.
키워드
GLYCOSIDASE INHIBITORY-ACTIVITY; ALPHA-GLUCOSIDASE INHIBITOR; STEREOSELECTIVE-SYNTHESIS; EFFICIENT SYNTHESIS; OLEFIN METATHESIS; BUILDING-BLOCK; DEOXYMANNOJIRIMYCIN; NOJIRIMYCIN; ANALOGS; PIPERIDINE
- 제목
- Asymmetric synthesis of 1-deoxyazasugars from chiral aziridines
- 저자
- Singh, Alok; Kim, Bongchan; Lee, Won Koo; Ha, Hyun-Joon
- 발행일
- 2011
- 유형
- Article
- 권
- 9
- 호
- 5
- 페이지
- 1372 ~ 1380