Facile Preparation of Ultrasmall Void Metallic Nanogap from Self-Assembled Gold-Silica Core-Shell Nanoparticles Monolayer via Kinetic Control

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초록

A facile preparation of ultrasmall 1-2 nm void metallic nanogaps on various solid substrates is proposed by utilizing the self-assembly of a uniform gold-silica core-shell nanoparticle monolayer at interfaces and chemical etching. The ultrasmall void metallic nanogap shows key advantages such as a strong near-field enhancement and free diffusion of analytes to the gap, which are useful in molecular sensing and monitoring. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

키워드

gold-silica core-shell nanoparticlesinterfacial self-assemblykinetic controlsurface-enhanced Raman spectroscopyvoid metallic nanogapsENHANCED RAMAN-SCATTERINGPLASMONIC NANOPARTICLESOPTICAL-PROPERTIESNM GAPSSPECTROSCOPYSERSINTERFACEARRAYSDIMERSCHEMISTRY
제목
Facile Preparation of Ultrasmall Void Metallic Nanogap from Self-Assembled Gold-Silica Core-Shell Nanoparticles Monolayer via Kinetic Control
저자
Shin, YunaSong, JihwanKim, DongchoulKang, Taewook
DOI
10.1002/adma.201501163
발행일
2015-08-05
유형
Article
저널명
Advanced Materials
27
29
페이지
4344 ~ 4350