Facile Preparation of Ultrasmall Void Metallic Nanogap from Self-Assembled Gold-Silica Core-Shell Nanoparticles Monolayer via Kinetic Control

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102
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101

초록

A facile preparation of ultrasmall 1-2 nm void metallic nanogaps on various solid substrates is proposed by utilizing the self-assembly of a uniform gold-silica core-shell nanoparticle monolayer at interfaces and chemical etching. The ultrasmall void metallic nanogap shows key advantages such as a strong near-field enhancement and free diffusion of analytes to the gap, which are useful in molecular sensing and monitoring. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

키워드

gold-silica core-shell nanoparticles; interfacial self-assembly; kinetic control; surface-enhanced Raman spectroscopy; void metallic nanogaps; ENHANCED RAMAN-SCATTERING; PLASMONIC NANOPARTICLES; OPTICAL-PROPERTIES; NM GAPS; SPECTROSCOPY; SERS; INTERFACE; ARRAYS; DIMERS; CHEMISTRY
제목
Facile Preparation of Ultrasmall Void Metallic Nanogap from Self-Assembled Gold-Silica Core-Shell Nanoparticles Monolayer via Kinetic Control
저자
Shin, Yuna; Song, Jihwan; Kim, Dongchoul; Kang, Taewook
DOI
10.1002/adma.201501163
발행일
2015-08-05
유형
Article
저널명
Advanced Materials
권
27
호
29
페이지
4344 ~ 4350