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Enantioselective Total Synthesis of (-)-Clavosolide A and B
- Son, Jung Beom;
- Kim, Si Nae;
- Kim, Na Yeong;
- Hwang, Min-ho;
- Lee, Wonsun;
- ... Lee, Duck Hyung
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10초록
Enantioselective total synthesis of (-)-clavosolide A and B was reported in full including the synthesis of proposed structure of (-)-clavosoldie A (1), revised structure of (-)-clavosoldie A (5), and revised structure of (-)-clavosoldie B (6). The relative and absolute stereochemistries of the natural products were confirmed unambiguously by comparing the optical rotation values and H-1 and C-13 NMR spectra of them.
키워드
Enantioselective total synthesis; Clavosolide A; Clavosolide B; MARINE MACROLIDE SYNTHESIS; ALDOL REACTIONS; ASYMMETRIC-SYNTHESIS; STEREOCONTROLLED SYNTHESIS; SELECTIVE REDUCTIONS; ALLYLIC ALCOHOLS; ALKYL-HALIDES; GLYCOSIDES; CYCLOPROPANATION; ANALOGS
- 제목
- Enantioselective Total Synthesis of (-)-Clavosolide A and B
- 저자
- Son, Jung Beom; Kim, Si Nae; Kim, Na Yeong; Hwang, Min-ho; Lee, Wonsun; Lee, Duck Hyung
- 발행일
- 2010-03-20
- 유형
- Article
- 권
- 31
- 호
- 3
- 페이지
- 653 ~ 663