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Macrocyclic lactam synthesis via a ring expansion reaction: Construction of the cripowellin skeleton
- Moon, B;
- Han, S;
- Yoon, Y;
- Kwon, H
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23초록
The cripowellin ring skeleton, a macrocyclic [2.3.5]-bicyclic ketolactam, was smoothly generated via construction of a spiro(benzazepin-cyclohexane-1, 3-dione) employing oxidative cyclization as a key step and a subsequent ring expansion reaction.
키워드
HYPERVALENT IODINE(III) REAGENT; PHENOLIC COUPLING REACTION; AMARYLLIDACEAE ALKALOIDS; CONVENIENT SYNTHESIS; DERIVATIVES; CYCLIZATION; ANNULATION
- 제목
- Macrocyclic lactam synthesis via a ring expansion reaction: Construction of the cripowellin skeleton
- 저자
- Moon, B; Han, S; Yoon, Y; Kwon, H
- 발행일
- 2005-03-17
- 유형
- Article
- 저널명
- Organic Letters
- 권
- 7
- 호
- 6
- 페이지
- 1031 ~ 1034
- 언어
- ENG
- 출판사
- American Chemical Society
- 발행국가
- 미국
- 분량
- 4 페이지
- ISSN
- E 1523-7052
P 1523-7060