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Enantioselective synthesis of the C14-C25 portion of the cytotoxic natural product, amphidinolide B1
- Lee, DH;
- Rho, MD
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The C14-C25 portion of the cytotoxic natural product, amphidinolide B1 (1), was synthesized enantioselectively using Myers asymmetric alkylation protocol, epoxide opening with higher order cuprate, Sharpless asymmetric epoxidation of allylic alcohol 17, and Sharpless asymmetric dihydroxylation of 24 as key steps. (C) 2000 Elsevier Science Ltd. All rights reserved.
키워드
TOP HALF; MOIETY; PSEUDOEPHEDRINE; KETONES
- 제목
- Enantioselective synthesis of the C14-C25 portion of the cytotoxic natural product, amphidinolide B1
- 저자
- Lee, DH; Rho, MD
- 발행일
- 2000-04-08
- 유형
- Article
- 권
- 41
- 호
- 15
- 페이지
- 2573 ~ 2576
- 언어
- ENG
- 출판사
- Elsevier BV
- 발행국가
- 영국
- 분량
- 4 페이지
- ISSN
- P 0040-4039