Vapor-liquid equilibria for the 1,1,1,2-tetrafluoroethane (HFC-134a) plus n-butane (R-600) system

  • Lim, Jong Sung
  • Seong, Gimyeong
  • Roh, Hee-Kook
  • Byun, Hun-Soo
Citations

WEB OF SCIENCE

25
Citations

SCOPUS

26

초록

Isothermal vapor-liquid equilibrium data for the binary mixture of 1,1,1,2-tetrafluoroethane (HFC-134a) + normal butane (R600) were measured at 273.15, 283.15, 293.15, 303.15, 313.15, and 323.15 K, respectively. The experiments were carried out using a continuous circulation-type equilibrium apparatus to measure temperature, pressure, and the compositions of the liquid and vapor phases. The experimental data were correlated with the Peng-Robinson equation of state (PR EOS) using the Wong-Sandler (W-S) mixing rule. Calculated results showed good agreement with experimental data. It was found that this system has very strong positive azeotropes for all the temperature ranges studied here.

키워드

ALTERNATIVE REFRIGERANT MIXTURESPHASE-EQUILIBRIAPENTAFLUOROETHANE HFC-125DIFLUOROMETHANE HFC-32BINARY-SYSTEMSMIXING RULEISOBUTANEHFC-227EAPRESSURESTATE
제목
Vapor-liquid equilibria for the 1,1,1,2-tetrafluoroethane (HFC-134a) plus n-butane (R-600) system
저자
Lim, Jong SungSeong, GimyeongRoh, Hee-KookByun, Hun-Soo
DOI
10.1021/je700041v
발행일
2007-07
유형
Article
저널명
Journal of Chemical and Engineering Data
52
4
페이지
1313 ~ 1318